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Image Search Results
Journal: The Analyst
Article Title: Quantitative HPLC-ICP-MS analysis of antimony redox speciation in complex sample matrices: new insights into the Sb-chemistry causing poor chromatographic recoveries.
doi: 10.1039/c0an00796j
Figure Lengend Snippet: Fig. 3 HPLC-ICP-MS chromatogram of an ascorbic acid–Sb(V) mixture 8 h after dilution in the mobile phase (I) or after 8½ h treatment with 1 M HCl, 100 mM citric acid and 30 mM EDTA (II). Mobile phase: 100 mM citrate, pH 4.5 (B).
Article Snippet: The size of the detected complexes was estimated with the
Techniques:
Journal: The Analyst
Article Title: Quantitative HPLC-ICP-MS analysis of antimony redox speciation in complex sample matrices: new insights into the Sb-chemistry causing poor chromatographic recoveries.
doi: 10.1039/c0an00796j
Figure Lengend Snippet: Fig. 2 HPLC-ICP-MS chromatogram of an ascorbic acid–Sb(V) mixture 4½ h after dilution in the mobile phase (I) or after 3 h treatment with 1 M HCl and 30 mM EDTA (II). Mobile phase: 20 mM EDTA and 2 mM phthalic acid at pH 4.5 (A).
Article Snippet: The size of the detected complexes was estimated with the
Techniques:
Journal: The Analyst
Article Title: Quantitative HPLC-ICP-MS analysis of antimony redox speciation in complex sample matrices: new insights into the Sb-chemistry causing poor chromatographic recoveries.
doi: 10.1039/c0an00796j
Figure Lengend Snippet: Fig. 5 HPLC-ICP-MS chromatogram of a cell extract diluted in the mobile phase (6 h after dilution, I); or treated with 1 M HCl and 100 mM citrate for 2 h (II). Mobile phase: 100 mM citrate, pH 4.5 (B). (Sb(V) elutes in two peaks as discussed in the section on optimisation of the chromatographic method.)
Article Snippet: The size of the detected complexes was estimated with the
Techniques:
Journal: The Analyst
Article Title: Quantitative HPLC-ICP-MS analysis of antimony redox speciation in complex sample matrices: new insights into the Sb-chemistry causing poor chromatographic recoveries.
doi: 10.1039/c0an00796j
Figure Lengend Snippet: Fig. 4 HPLC-ICP-MS chromatogram of Pentostam 3 h after dilution in the mobile phase (I) or after 2 h treatment with 1 M HCl, 100 mM citric acid and 30 mM EDTA (II). Mobile phase: 100 mM citrate, pH 4.5 (B).
Article Snippet: The size of the detected complexes was estimated with the
Techniques: